Which form is used to reflect payments from the petty cash fund?

The Petty Cash Voucher is the correct choice because it is specifically designed to document and reflect payments made from the petty cash fund. This form serves as a record for small expenditures that do not warrant the use of regular accounting processes. The voucher includes details about the amount disbursed, the purpose of the payment, and typically requires a signature from the person receiving the funds, thereby providing accountability for the use of petty cash.

In contrast, an Expense Report is generally used for documenting broader expenses incurred by employees, often related to travel or official business, and not specifically tied to the petty cash fund. A Financial Statement provides an overall view of a company's financial health, summarizing revenues, expenses, and other financial metrics, which does not directly pertain to the individual transactions made from petty cash. The Payment Request Form is utilized for larger, formal requests for funds and disbursements that exceed the petty cash limits, making it unsuitable for the specific tracking of petty cash usage. Thus, the Petty Cash Voucher is uniquely suited for this purpose, ensuring transparency and proper management of the petty cash fund.